thermal properties of wood-plastic composites prepared from hemicellulose-extracted wood flour

نویسندگان

علی اکبر عنایتی

امید حسینایی

سی چوان وانگ

سیداحمد میرشکرایی

مهدی تجویدی

چکیده

hemicellulose of southern yellow pine wood spices was extracted by pressurized hot water at three different temperatures: 140°c, 155°c and 170°c. compounding with pp (polypropylene) was performed by extrusion after preparing wood flour and sieving to determine its mesh size. the ratio of wood to polymer was 50:50 based on oven-dry weight of wood flour. all extraction treatments and control samples were compounded under two sets of conditions, without and with 2% mapp as coupling agent. injection molding was used to make tensile test samples (dogbone) from the pellets made by extrusion. thermal properties of wood-plastic composites were studied by tga and dsc while the thermal stability of pretreated wood flours, pp and mapp were studied by tga as well. the greater weight loss of wood materials was an indication that higher treatment temperature increases the extractability of hemicellulose. the removal of hemicellulose by extraction improves thermal stability of wood flour, especially for extraction at 170°c. wood-plastic composites made from extracted fibers at 170°c showed the highest thermal stability. coupling agent did not have a significant effect on thermal stability but it improved the degree of crystallinity of the composites.surface roughness of wood fiber increased after treatment. extraction of hemicellulose increased the degree of crystallinity but it was not significant except for samples from treated wood flour at 170°c and with mapp.

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